In equal circles angles have the same ratio as the circumferences on which they stand, whether they stand at the centres or at the circumferences.
Proof
Use III.27 (equal arcs subtend equal central angles in equal circles)
to set up an equimultiples test: for any positive integers m, n,
m copies of one angle correspond to m copies of its arc, and the
order of mα versus nβ matches the order of m⋅arc(α) versus n⋅arc(β). This is
exactly Definition V.5 for α:β=arc(α):arc(β). The inscribed-angle case follows from III.20
(inscribed angle is half the central).